Rutile occurrence and trace element behavior in medium-grade metasedimentary rocks: example from the Erzgebirge, Germany     

George Luiz Luvizotto  Thomas Zack  Silke Triebold  Hilmar von Eynatten 《Mineralogy and Petrology》2009,97(3-4):233-249

Metamorphic textures in medium-grade (~500–550°C) metasedimentary rocks from the Erzgebirge give evidence of prograde rutile crystallization from ilmenite. Newly-crystallized grains occur as rutile-rich polycrystalline aggregates that pseudomorph the shape of the ilmenites. In-situ trace element data (EMP and SIMS) show that rutiles from the higher-grade samples record large scatter in Nb content and have Nb/Ti ratios higher than coexisting ilmenite. This behavior can be predicted using prograde rutile crystallization from ilmenite and indicates that rutiles are reequilibrating their chemistry with remaining ilmenites. On the contrary, rutiles from the lowest grade samples (~480°C) have Nb/Ti ratios that are similar to the ones in ilmenite. Hence, rutiles from these samples did not equilibrate their chemistry with remaining ilmenites. Our data suggest that temperature may be one of the main factors determining whether or not the elements are able to diffuse between the phases and, therefore, reequilibrate. Newly-crystallized rutiles yield temperatures (from ~500 to 630°C, Zr-in-rutile thermometry) that are in agreement with the metamorphic conditions previously determined for the studied rocks. In quartzites from the medium-grade domain (~530°C), inherited detrital rutile grains are detected. They are identified by their distinct chemical composition (high Zr and Nb contents) and textures (single grains surrounded by fine grained ilmenites). Preliminary calculation, based on grain size distribution of rutile in medium-grade metapelites and quartzites that occur in the studied area, show that rutiles derived from quartzites can be anticipated to dominate the detrital rutile population, even if quartzites are a minor component of the exposure.  相似文献   

Geochemistry and mineralogy of shallow alluvial aquifers in Daudkandi upazila in the Meghna flood plain, Bangladesh   总被引：1，自引：0，他引：1  

M. Aziz Hasan  Mattias von Br?mssen  Prosun Bhattacharya  Kazi Matin Ahmed  Arif Mohiuddin Sikder  Gunnar Jacks  Ondra Sracek 《Environmental Geology》2009,57(3):499-511

The shallow alluvial aquifers of the delta plains and flood plains of Bangladesh, comprises about 70% of total land area are mostly affected by elevated concentrations of arsenic (As) in groundwater exposing a population of more than 35 million to As toxicity. Geochemical studies of shallow alluvial aquifer in the Meghna flood plain show that the uppermost yellowish grey sediment is low in As (1.03 mg/kg) compared to the lower dark grey to black sediment (5.24 mg/kg) rich in mica and organic matter. Sequential extraction data show that solid phase As bound to poorly crystalline and amorphous metal (Fe, Mn, Al)-oxyhydroxides is dominant in the grey to dark grey sediment and reaches its maximum level (3.05 mg/kg) in the mica rich layers. Amount of As bound to sulphides and organic matter also peaks in the dark grey to black sediment. Vertical distributions of major elements determined by X-ray fluorescence (XRF) show that iron (Fe₂O₃), aluminum (Al₂O₃) and manganese (MnO) follow the general trend of distribution of As in the sediments. Concentrations of As, Mn, Fe, HCO₃ ⁻, SO₄ ²⁻ and NO₃ ⁻ in groundwater reflect the redox status of the aquifer and are consistent with solid phase geochemistry. Mineralogical analysis by X-ray diffraction (XRD) and scanning electron microscopy (SEM) fitted with energy dispersive X-ray spectrometer (EDS) revealed dominance of crystalline iron oxides and hydroxides like magnetite, hematite and goethite in the oxidised yellowish grey sediment. Amorphous Fe-oxyhydroxides identified as grain coating in the mica and organic matter rich sediment suggests weathering of biotite is playing a critical role as the source of Fe(III)-oxyhydroxides which in turn act as sink for As. Presence of authigenic pyrite in the dark grey sediment indicates active reduction in the aquifer.  相似文献   

Non-LTE radiative transfer for sub-millimeter water lines in Comet 67P/Churyumov-Gerasimenko     

Seungwon Lee  Paul von Allmen  Samuel Gulkis 《Icarus》2011,215(2):721-731

The European Space Agency (ESA) Rosetta spacecraft (Schulz, R., Alexander, C., Boehnhardt, H., Glassmeier, K.H. (Eds.) [2009]. “ROSETTA - ESA”) will encounter Comet 67P/Churyumov-Gerasimenko in 2014 and spend the next 18 months in the vicinity of the comet, permitting very high spatial and spectral resolution observations of the coma and nucleus. During this time, the heliocentric distance of the comet will change from ∼3.5 AU to ∼1.3 AU, accompanied by an increasing temperature of the nucleus and the development of the coma. The Microwave Instrument for the Rosetta Orbiter (MIRO) will observe the ground-state rotational transition (1₁₀-1₀₁) of H₂¹⁶O at 556.936 GHz, the two isotopologues H₂¹⁷O and H₂¹⁸O and other molecular transitions in the coma during this time (Gulkis, S. et al., [2007]. MIRO: Microwave Instrument for Rosetta Orbiter. Space Sci. Rev. 128, 561-597).The aim of this study is to simulate the water line spectra that could be obtained with the MIRO instrument and to understand how the observed line spectra with various viewing geometries can be used to study the physical conditions of the coma and the water excitation processes throughout the coma. We applied an accelerated Monte Carlo method to compute the excitations of the seven lowest rotational levels (1₀₁, 1₁₀, 2₁₂, 2₂₁, 3₀₃, 3₁₂, and 3₂₁) of ortho-water using a comet model with spherically symmetric water outgassing, density, temperature and expansion velocity at three different heliocentric distances 1.3 AU, 2.5 AU, and 3.5 AU. Mechanisms for the water excitation include water-water collisions, water-electron collisions, and infrared pumping by solar radiation.Synthetic line spectra are calculated at various observational locations and directions using the MIRO instrument parameters. We show that observations at varying viewing distances from the nucleus and directions have the potential to give diagnostic information on the continuum temperature and water outgassing rates at the surface of the nucleus, and the gas density, expansion velocity, and temperature of the coma as a function of distance from the nucleus. The gas expansion velocity and temperature affect the spectral line width and frequency shift of the line from the rest frequency, while the gas density (which is directly related to the outgassing rate) and the line excitation temperature determine the antenna temperature of the absorption and emission signal in the line profile.  相似文献   

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)     

Lucien von Gunten  Oliver Heiri  Christian Bigler  Jacqueline van Leeuwen  Carlo Casty  André F. Lotter  Michael Sturm 《Journal of Paleolimnology》2008,39(3):283-299

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.  相似文献   

Variations of vertical velocity in the deep oceans simulated by a 1/10° OGCM     

Jin-Song von Storch 《Ocean Dynamics》2010,60(3):759-770

This paper analyzes variations of vertical velocity w simulated by the 1/10° Ocean General Circulation Model for the Earth Simulator (OFES). Strong w-variability is found in the deep oceans. When w is WKBJ-normalized, the standard deviation averaged over the Southern Ocean increases with depth and is larger than 8 × 10^− 3 cm/s throughout the water column below 1,500 m. Evidences are presented that link this w-variability to internal waves generated by quasi-steady currents over topography. The aliasing errors in lag-3-day correlations suggest a bottom generation of near-inertial waves. A scale analysis indicates that vertically propagating waves that can be resolved by the OFES model are waves with frequencies of the order of inertial frequency and wavelengths comparable to the order of the grid size. The vertical energy flux associated with these waves is substantial. When integrated globally, the vertical energy flux is upward in the upper 4 km and reaches maximum values of about 0.8 TW at about 1 to 2 km depth. Thus, the w-variability in the 1/10° OFES integration points not only to a strong bottom generation of near-inertial internal waves in the deep Southern Ocean but also to the possibility that the power provided by internal waves generated by non-tidal currents over topography can be comparable to the power provided by internal waves generated by tidal flows over topography.  相似文献   

Spatio-temporal relationships between habitat types and microbial function of an upland floodplain     

Pascal Bodmer  Remo Freimann  Stefanie von Fumetti  Christopher T. Robinson  Michael Doering 《Aquatic Sciences - Research Across Boundaries》2016,78(2):241-254

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Assessment of three temperature reconstruction methods in the virtual reality of a climate simulation     

Hans von Storch  Eduardo Zorita  Fidel González-Rouco 《International Journal of Earth Sciences》2009,98(1):67-82

The performance of statistical climate reconstruction methods in the pre-instrumental period is uncertain, as they are calibrated in a short instrumental period but applied to much longer reconstructions time spans. Here, the virtual reality created by a climate simulation of the past millennium with the model ECHO-G is used as a test bed of three methods to reconstruct the annual Northern Hemisphere temperature. The methods are Composite plus Scaling, the inverse regression method of Mann et al. (Nature 392:779–787, 1998) and a direct principal-components regression method. The testing methodology is based on the construction of pseudo-proxies derived from the climate model output, the application of each of these methods to pseudo-proxy timeseries, and the comparison of their result with the simulated mean temperature. Different structures of the noise have been used to construct pseudo-proxies, ranging from the simulated grid-point precipitation. Also, one sparse and one denser pseudo-proxy network, co-located with two real networks, have been considered. All three methods underestimate the simulated variations of the Northern Hemisphere temperature, but the Composite plus Scaling method clearly displays a better performance and is robust against the different noise models and network size. The most relevant factor determining the skill of the reconstruction appears to be the network size, whereas the different noise models tend to yield similar results.  相似文献   

Induced seismicity during the construction of the Gotthard Base Tunnel, Switzerland: hypocenter locations and source dimensions     

Stephan Husen  Edi Kissling  Angela von Deschwanden 《Journal of Seismology》2013,17(1):63-81

A series of 112 earthquakes was recorded between October 2005 and August 2007 during the excavation of the MFS Faido, the southernmost access point of the new Gotthard Base Tunnel. Earthquakes were recorded at a dense network of 11 stations, including 2 stations in the tunnel. Local magnitudes computed from Wood?CAnderson-filtered horizontal component seismograms ranged from ?1.0 to 2.4; the largest earthquake was strongly felt at the surface and caused considerable damage in the tunnel. Hypocenter locations obtained routinely using a regional 3-D P-wave velocity model and a constant Vp/Vs ratio 1.71 were about 2?km below the tunnel. The use of seismic velocities calibrated from a shot in the tunnel revealed that routinely obtained hypocenter locations were systematically biased to greater depth and are now relocated to be on the tunnel level. Relocation of the shot using these calibrated velocities yields a location accuracy of 25?m in longitude, 70?m in latitude, and 250?m in focal depth. Double-difference relative relocations of two clusters with highly similar waveforms showed a NW?CSE striking trend that is consistent with the strike of mapped faults in the MFS Faido. Source dimensions computed using the quasidynamic model of Madariaga (Bull Seismo Soc Am 66(3):639?C666, 1976) range from 50 to 170?m. Overlapping source dimensions for earthquakes within the two main clusters suggests that the same fault patch was ruptured repeatedly. The observed seismicity was likely caused by stress redistribution due to the excavation work in the MFS Faido.  相似文献   

Discovery of Ordovician–Silurian metamorphic monazite in garnet metapelites of the Alpine External Aiguilles Rouges Massif     

Bernhard Schulz  Jürgen F. von Raumer 《Swiss Journal of Geoscience》2011,104(1):67-79

The pre-Mesozoic, mainly Variscan metamorphic basement of the Col de Bérard area (Aiguilles Rouges Massif, External domain) consists of paragneisses and micaschists together with various orthogneisses and metabasites. Monazite in metapelites was analysed by the electron microprobe (EMPA-CHIME) age dating method. The monazites in garnet micaschists are dominantly of Variscan age (330–300 Ma). Garnet in these rocks displays well developed growth zonations in Fe–Mg–Ca–Mn and crystallized at maximal temperatures of 670°C/7 kbar to the west and 600°C/7–8 kbar to the east. In consequence the monazite is interpreted to date a slightly pressure-dominated Variscan amphibolite-facies evolution. In mylonitic garnet gneisses, large metamorphic monazite grains of Ordovician–Silurian (~440 Ma) age but also small monazite grains of Variscan (~300 Ma) age were discovered. Garnets in the mylonitic garnet gneisses display high-temperature homogenized Mg-rich profiles in their cores and crystallized near to ~800°C/6 kbar. The Ordovician–Silurian-age monazites can be assigned to a pre-Variscan high-temperature event recorded by the homogenised garnets. These monazite age data confirm Ordovician–Silurian and Devonian–Carboniferous metamorphic cycles which were already reported from other Alpine domains and further regions in the internal Variscides.  相似文献   

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years   总被引：1，自引：0，他引：1  

Pierre Francus  Hans von Suchodoletz  Michael Dietze  Reik V. Donner  Frédéric Bouchard  Ann‐Julie Roy  Maureen Fagot  Stefan Kröpelin 《Sedimentology》2013,60(4):911-934

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.  相似文献